The use of CFCs is now beginning to be phased out due to their damaging impact on the protective tropospheric ozone layer around the earth. The Montreal Protocol of 1987 and the subsequent Copenhagen agreement of 1992 mandate a reduction in the production of ozone depleting Chlorinated Fluorocarbon (CFC) refrigerants in a phased manner, with an eventual stop to all production by the year 1996.
In response, the refrigeration industry has developed two alternative refrigerants; one based on Hydrochloro Fluorocarbon (HCFC), and another based on Hydro Fluorocarbon (HFC). The HCFCs have a 2 to 10% ozone depleting potential as compared to CFCs and also, they have an atmospheric lifetime between 2 to 25 years as compared to 100 or more years for CFCs (Brandt, 1992).
However, even HCFCs are mandated to be phased out, and only the chlorine free (zero ozone depletion) HFCs would be acceptable. Until now, only one HFC based refrigerant, HFC 134a, has been developed. HCFCs are comparatively simpler to produce and the three refrigerants 22, 123, and 124 have been developed.
The use of HFCs and HCFCs results in slightly lower efficiencies as compared to CFCs, but this may change with increasing efforts being made to replace CFCs.
In response, the refrigeration industry has developed two alternative refrigerants; one based on Hydrochloro Fluorocarbon (HCFC), and another based on Hydro Fluorocarbon (HFC). The HCFCs have a 2 to 10% ozone depleting potential as compared to CFCs and also, they have an atmospheric lifetime between 2 to 25 years as compared to 100 or more years for CFCs (Brandt, 1992).
However, even HCFCs are mandated to be phased out, and only the chlorine free (zero ozone depletion) HFCs would be acceptable. Until now, only one HFC based refrigerant, HFC 134a, has been developed. HCFCs are comparatively simpler to produce and the three refrigerants 22, 123, and 124 have been developed.
The use of HFCs and HCFCs results in slightly lower efficiencies as compared to CFCs, but this may change with increasing efforts being made to replace CFCs.